Two-photon spectroscopy of the NaLi triplet ground state.
نویسندگان
چکیده
We employ two-photon spectroscopy to study the vibrational states of the triplet ground state potential (a3Σ+) of the 23Na6Li molecule. Pairs of Na and Li atoms in an ultracold mixture are photoassociated into an excited triplet molecular state, which in turn is coupled to vibrational states of the triplet ground potential. Vibrational state binding energies, line strengths, and potential fitting parameters for the triplet ground a3Σ+ potential are reported. We also observe rotational splitting in the lowest vibrational state.
منابع مشابه
Long-Lived Ultracold Molecules with Electric and Magnetic Dipole Moments.
We create fermionic dipolar ^{23}Na^{6}Li molecules in their triplet ground state from an ultracold mixture of ^{23}Na and ^{6}Li. Using magnetoassociation across a narrow Feshbach resonance followed by a two-photon stimulated Raman adiabatic passage to the triplet ground state, we produce 3×10^{4} ground state molecules in a spin-polarized state. We observe a lifetime of 4.6 s in an isolated m...
متن کاملDMRG studies of the properties of Low - lying states of Poly - para - phenylene ( PPP ) system
We report the symmetrized density matrix renormalization group (DMRG) study of neutral and doped oligomers of PPP system within an extended Hubbard model. Model parameters are determined by comparing the existing results for interacting small system. We compute a number of properties in the ground state as well as in the one-photon, two-photon and triplet states to completely characterize these...
متن کاملElectric-Field-Induced Triplet to Singlet Transition in Size-2 Trigonal Zigzag Graphene Nanoflake
Using Hartree-Fock Su-Sheriffer-Heeger (HF-SSH) model, we have studied the dependence of the energies of the ground (magnetic triplet state) and the first exited (nonmagnetic singlet state) states of the size-2 trigonal zigzag graphene nanoflake (size-2 NF) on the intensity of an external in plane static electric field at zero temperature. We identify a transition from the magnetic triplet stat...
متن کاملIntensity-Dependent Ultraviolet Laser Flash Excitation of Diphenylamine in Methanol: A Two-Photon Ionization Mechanism Involving the Triplet State
The UV laser flash excitation of diphenylamine in methanol at 308 nm leads to similar triplet decay routes as those found previously for N-methyldiphenylamine and triphenylamine. The temperature dependence of the diphenylamine triplet decay shows that both ring closure to form triplet dihydrocarbazole and intersystem crossing back to the ground state take place. The Arrhenius parameters for the...
متن کاملA study of the structure and bonding of small aluminum oxide clusters by photoelectron spectroscopy: AlxOy
The structure and bonding of aluminum oxide clusters, AlxOy ~x51–2, y51–5!, are studied with anion photoelectron spectroscopy ~PES! and are compared with preliminary ab initio calculations. The spectra were obtained at four detachment photon energies: 2.33, 3.49, 4.66, and 6.42 eV. The 6.42 eV spectrum for AlO reveals the X S ground state and two excited states of AlO. The 6.42 eV spectrum for ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 20 7 شماره
صفحات -
تاریخ انتشار 2018